Research
Bridging inorganic S(VI) and organic chemistry
We develop hexacoordinate sulfur(VI) fluoride chemistry — from fundamental gas-handling and reactivity to derivatization routes with direct application in organic synthesis.
Sulfur(VI) fluorides such as SF₆ are famously inert — which is exactly what makes selective, controlled derivatization of this coordination sphere so valuable once it's achievable. Our group works on the gas-handling chemistry and reagent design needed to open up this space, then translates the resulting functional groups into tools organic chemists can actually use on the bench.
OSFx
Pentafluorooxosulfate ([OSF₅]⁻) and related oxosulfur(VI) fluoride species. Once considered a chemical curiosity, this functional group is establishing itself as a valuable motif. Our work with Prof. Sebastian Riedel's group focuses on reservoir chemistry for selective SOF₄, SO₂F₂, and [OSF₅]⁻ release, and on expanding the accessibility of this chemistry for wider use.
NSFx
Nitrogen-containing S(VI)F derivatives are the core independent direction of the Hetero-SFₓ Laboratory. We investigate the synthesis, reactivity, and application of these species, aiming to translate fundamental inorganic fluorine chemistry toward modern organic synthesis.
Approach
How we work
Gas handling
Custom vacuum-line and gas-handling techniques for working safely and precisely with volatile S(VI)F species.
Derivatization
Selective functionalization strategies that convert reactive gaseous intermediates into stable, usable reagents.
Application
Translating new S(VI)F motifs into tools for organic synthesis, in collaboration with organic and inorganic groups alike.
Interested in this chemistry?
We welcome inorganic and organic chemists looking to expand their experimental and theoretical expertise at this interface.
See open positions